Abstract
Theoretical studies of low-energy electron-silane scattering are reported in which target polarization is included by using an ab initio optical potential. These calculations employ the complex Kohn scattering method and were undertaken both at the static-exchange level and with target polarization. A polarized virtual-orbital method, which was introduced in our earlier study of electron-methane scattering, was also employed in this study to generate a compact description of the closed channels included in the optical potential. Differential, integral, and momentum-transfer cross sections are reported at incident energies ranging from 0.2 to 20 eV. The computed total cross section shows a Ramsauer-Townsend minimum at 0.3 eV and a broad d-wave shape resonance at 3.0 eV. Excellent agreement is found between our polarized Kohn results and the recent experimental results of Wan, Moore, and Tossell [J. Chem. Phys. 91, 7340 (1989)].
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
More From: Physical review. A, Atomic, molecular, and optical physics
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.