Abstract
By taking into account slight interactions, i.e. spin–spin, spin–other-orbit and orbit–orbit interactions, in addition to spin–orbit interaction, the zero-field splitting of ground state and low excited states and g factors of ZnGa 2O 4:Cr 3+ crystal have been interpreted systematically. And the contributions to zero-field splitting arising from slight magnetic interaction and trigonal crystal field are investigated. It is found that there exist combined mechanism between magnetic interactions and trigonal crystal field.
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