Abstract

In this work, two d–d transition spectra and four EPR parameters g ∥, g ⊥, A ∥, A ⊥ of K 2PdCl 4/Cu 2+ are uniformly interpreted based on Zhao's crystal-field model. The calculation result is in good agreement with the experiment findings. The ligand spin-orbit coupling is neglected on the calculation, which is consistent with the ab initio result by Hillier et al. [J. Am. Chem. Soc. 98 (1976) 95]

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