Abstract

The transport in a temperature gradient of NbB2 and TaB2 by means of iodine in a vapour transport process has been studied in a horizontal silica tube. It was observed that the rate of transport under a constant temperature gradient was a function of the quantity of iodine and that at a constant temperature difference, transport was greatest at the highest practicable temperature. The mechanism of the processes involved is discussed in the light of the thermodynamic data available for the compounds involved.

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