Abstract

Potential risks of supply shortages for critical metals including rare-earth elements and yttrium (REY) have spurred great interest in commercial mining of deep-sea mineral resources. Deep-sea mud containing over 5,000 ppm total REY content was discovered in the western North Pacific Ocean near Minamitorishima Island, Japan, in 2013. This REY-rich mud has great potential as a rare-earth metal resource because of the enormous amount available and its advantageous mineralogical features. Here, we estimated the resource amount in REY-rich mud with Geographical Information System software and established a mineral processing procedure to greatly enhance its economic value. The resource amount was estimated to be 1.2 Mt of rare-earth oxide for the most promising area (105 km2 × 0–10 mbsf), which accounts for 62, 47, 32, and 56 years of annual global demand for Y, Eu, Tb, and Dy, respectively. Moreover, using a hydrocyclone separator enabled us to recover selectively biogenic calcium phosphate grains, which have high REY content (up to 22,000 ppm) and constitute the coarser domain in the grain-size distribution. The enormous resource amount and the effectiveness of the mineral processing are strong indicators that this new REY resource could be exploited in the near future.

Highlights

  • Have spurred great interest in commercial mining of deep-sea mineral resources

  • Deep-sea mud containing over 5,000 ppm total rare-earth elements and yttrium (REY) content was discovered in the western North Pacific Ocean near

  • REY-rich mud having a maximum of almost 8,000 ppm of total REY content (ΣREY) was confirmed

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Summary

Results and Discussion

After the KR13-02, MR13-E02, and KR14-02 cruises, three additional research cruises (MR14-E02, MR15-E01 Leg 2, and MR15-02) were conducted to reveal the detailed distribution of highly to extremely REY-rich mud in the southern part of the Minamitorishima EEZ (Fig. 1)[8,9]. During these cruises, REY-rich mud having a maximum of almost 8,000 ppm of total REY content (ΣREY) was confirmed. Shows the highest REY resource potential, with an average ΣREY of more than 1,700 ppm Our measurements show that the average ΣREY in BCP exceeds 15,000 ppm (up to 22,000 ppm), and that BCP can generally account for the total REY in highly/extremely REY-rich mud (Fig. 3).

The BCP grains in marine sediment and in highly to extremely
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