Abstract
AbstractInvestigations in the temperature range −45 ≤ θ/°C ≤ + 25 on LiBF4 solutions in dimethoxyethane from infinite dilution to saturation permit to exemplify the features of conductance in solvents of low permittivity. Conductance measurements on thoroughly purified materials with the help of a measuring equipment known to produce precise data yield a complete set of conductance curves from infinite dilution to saturation at all temperatures of the program. The conductance curves show a minimum and a maximum of equivalent conductance and the change from positive to negative and once more to positive temperature coefficients of conductance. Various methods both for the evaluation of the limiting conductances, Λ∞, and the formation constants of ion pairs, KA, triple ions, KT, are critically discussed and reliable data for the LiBF4 solutions in dimethoxyethane at all temperatures of the program are communicated.
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