Abstract
Treatment of dichloromethane solutions of the heteronuclear cluster compounds [M 2Ru 4(μ 3-H) 2{μ-Ph 2P(CH 2) 2PPh 2}(CO) 12] (M = Cu or Ag) with dichloromethane solutions containing the appropriate quantities of the complex [Ag(NCMe) 4]PF 6 or [AuCl(SC 4H 8)] results in the replacement of either one or both of the Group IB metals M by silver or gold atoms. The products from the Group IB metal exchange reactions are obtained in ca. 65–75% yield.
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