Abstract
Abstract The reaction between C 3 F 7 I and CrCl 2 (CH 3 CN) 2 in the presence of pyridine allows the isolation of C 3 F 7 CrCl 2 py 3 together with a CrICl 2 -pyridine complex. Similar complexes can be prepared using 2,2′-bipyridyl, 2,2′,2″-terpyridyl and 1,10-phenanthroline. The latter complexes are resistant to hydrolysis whereas C 3 F 7 CrCl 2 py 2 is rapidly hydrolysed to a pentafluoroalkyl aquo species.
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