Abstract
It is suggested that the facile low-temperature solid-state inter-conversion of the α- and β-phases of 5-methyl-1-thia-5-azoniacyclo-octane 1-oxide perchlorate occurs on recurrent (102) type planes. The mechanism, which is likely to be of general validity in organic solid-state chemistry, dispenses with the need to postulate co-operative conformational changes on half of the molecular cations (mol-ions) in each row and in each column, and also explains all the known experimental facts relating to the transition.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Journal of the Chemical Society, Perkin Transactions 2
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
