Abstract

Heterogeneous exchange process between iodide ions in the liquid and solid phase in silver iodide suspensions depends on concentration and chemical nature of the tenside present. Between the critical coagulation and stabilization concentrations of the ionic tenside with the electrical sign opposite to the electrical sign of the silver iodide particles, the AgI—I−(131I−) exchange becomes accelerated. Ultramicroscopic microelectrophoresis, radiometry, X-ray diffractometry and the results of the optical measurements indicate various structures of the interphase layer in the ‘silver iodide — tenside’ systems with a complex dependence on the conditions of the formation.

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