Abstract
The reaction between the dihydride of decacarbonyltriosmium [H 2Os 3(CO) 10] and phenyl arsine oxide (PAO) in benzene yields only one product [Os 3(O) 9(μ-H){μ-PhAs(O)OAsPh}] ( 1), which is characterized by high resolution mass spectrometry (HRMS), Fast Atomic Bombardment Mass Spectrometry (FAB) +, IR, 1H and 13C NMR, and single crystal X-ray diffraction. The solid state X-ray diffraction study of compound ( 1) shows that the molecule is polycyclic and has an osmium triangle with a bridging hydride bonded to a PhAs(O)-O-AsPh ligand.
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