Abstract
The self‐assembly of porphine molecules on NaCl pre‐covered Cu(110) surface has been investigated at a single molecular level by scanning tunneling microscopy. The pre‐grown NaCl stripe pattern has been partly interrupted due to the adsorption of porphine molecules at RT. Annealing the sample at 333 K and 423 K gradually promotes the formation of self‐assembly network composed of porphine molecules and Cu atoms. Annealing at 473 K helps to convert this self‐assembly structure into organometallic nanoribbon through C–Cu–C connecting.
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