Abstract
Aluminum is commonly observed in the surface region of SiC fibers in hot-pressed glass ceramic matrix composites. It is believed to be the result of interface reactions with Al-containing matrices. However, the influence of aluminum migration on the evolution of interphases, especially carbon enrichment, still remains unknown. In this study, reaction couples between an alumino-silicate glass and silicon-oxycarbide were used to study mass transport and interphase formation. The silicon oxycarbide, synthesized using a sol-gel process, was used to simulate the reactive phase of polymer-derived SiC fibers; in some case, it was doped with Al. A strong influence of aluminum on the carbon enrichment was observed. Using a thermodynamic model, the mechanism of the interphase evolution will be discussed.
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