Abstract
The effect of the functional group on the partial rate constants of the reactions of the tert -butylper- oxy radical with CH bonds in the cyclohexyloxy moiety of cyclohexyl acetate at 333 K was studied by the Howard-Ingold method. The ester group activates the CH bond at the 1-position and deactivates the CH bonds at the 3-position and, especially, the 2-position. The reactivity of CH bonds at the 4-position is close to the reac- tivity of CH bonds in cyclohexane.
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