Abstract

Trichloroidomethane reacts with a number of alkyls and aryls of Group VB elements forming 1:1 adducts, R 3M.CCl 3I. The compounds are unstable in the presence of moisture. Conductimetric titrations show that the compounds are not quaternary salts similar to the di-iodo derivatives of the organometallic compounds. The failure of carbon tetrachloride to react in a similar way to trichloroiodomethane indicates that an MI bond is most probably formed.

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