Abstract
Peroxydisulfuryl difluoride, F S O O OO S O O F , reacts with antimony pentachloride to give chlorine and a product containing antimony (V) in combination with the fluorosulphate group. When the reagents are used in such proportions that antimony pentafluorosulphate might reasonably be expected as a product, this substance, if present, is impure. The resulting material tends to decompose slowly with formation of SO 3 and S 2O 5F 2 but it may at first contain over four fluorosulphate groups per atom of antimony. When S 2O 6F 2 is used in excess as a reactant, part of the chlorine of the SbCl 5 is oxidized to a positive oxidation state and remains in the product containing antimony.
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