Abstract
Some oximes reacted with cyclic phosphorus esters derived from o-hydroxybenzyl alcohol and its analogues to give phenolic and acidic products. The phenolic products were O-o-hydroxybenzyl derivatives of the oximes and the acidic products were phosphoric-oximinic anhydrides. The rate of reaction decreased in the order; phcnylphosphonate>phenyl phos-phate>alkyl phosphate. Phosphoramide ester was not reactive. Three of eight tested oximes, monoisonitrosoacetone, pyridine-2-aldoxime mcthiodidc and salicylaldoximc, were reactive. The reaction mechanism was discussed.
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