Abstract
Abstract When bis (acetylacetonato)cobalt(II) is allowed to react with twice molar quantity of bromine in dichloromethane, cobalt(II) bromide and γ-bromoacetylacetone are produced ultimately. From a deep blue solution of an equimolar reaction mixture at 0°C an intermediary product was isolated and characterized to be dimeric bromo(acetylacetonato)cobalt(II) by means of elemental analysis and molecular weight determination. The structure of this compound was inferred to be tetrahedral from absorption spectra and magnetic data. Acetylacetonate groups were supposed to act as bridging ligands on the basis of IR data in the lower frequency region. Dibromobis(acetylacetonato)dicobalt(II) was also derived from dibromo(acetylacetone)cobalt(II) by the reaction with sodium acetylacetonate in acetylacetone at 0°C.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
