Abstract
Electrical conductivity measurements on solutions of the trinitratonitrosylruthenium complex in water indicate that it is an acid for which the first dissociation constant has a value of 0·014 mole litre −1. The partition coefficient of the complex between solutions in water and in tri- n-butyl phosphate (TBP) has been calculated from its observed distribution between these solvents and the degree of dissociation of the complex in aqueous solutions. The hydrolysis of the complex in nitric acid solutions has been shown to occur initially by a first-order rate process with a rate constant k = 0·046 min −1 at 25°C.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
