Abstract
Experiments in dimethyl sulphoxide and dimethylacetamide show that ‘chloroferric phthalocyanine’ is most probably a hydrochloride of ferrous phthalocyanine. Evidence is presented to show that chloride ion is acting as an axial ligand at a ferrous centre. The proton modifies the phthalocyanine ring, presumably being attached to an azomethine bridge. These results are discussed in the light of previous ones.
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