Abstract

Evaporation experiments from sand columns with restricted and unrestricted water tables were carried out to elucidate the mechanism of evaporation from bare land. Turbulent airflow was applied to the exposed surface layer. The transient development of the deuterium composition of liquid water in the sand columns was measured by a microdistillation technique during the experiments. Turbulent airflow affected the evaporative process of water vapour transfer and the deuterium distribution at relatively shallow depths in the columns. The attainment of a steady evaporation rate and deuterium profile was not obtained in either the restricted or unrestricted water table cases until significant time had elapsed. In the unrestricted water table case, the transient processes of evaporation rate, depth of the evaporation front, water table depth and the development of the deuterium concentration profile show a characteristic behaviour that may be described by a similarity solution for part of the experimental duration. Significant enrichment of deuterium occurs in the liquid-vapour region and at the upper zone of the liquid region with time. The isotopic enrichment does not affect the physical process of evaporation of liquid water. Information on the transient development of the deuterium concentration profile is very useful for understanding the nature of liquid water and water vapour movement in the columns, and estimation of the depth of the evaporating front is an important index in bare land evaporation.

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