Abstract
Second-order rate constants for the reaction between the chloropentamminecobalt(III) and hydroxide ions were measured spectrophotometrically at low ionic strengths at 0·56, 7·05 and 14·17°C. The variation of rate constants with ionic strength follows the predictions of the Brönsted-Bjerrum theory. At zero ionic strength the variation of the rate constant with respect to temperature is reproduced by the equation. k 2 0=1·514×10 20 exp(−27.240/RT)1. m −1 sec −1
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