Abstract

Second-order rate constants for the reaction between bromopentamminecobalt (III) and hydroxide ions were measured spectrophotometrically at low ionic strengths in the temperature range 2·8–20°. The variation of rate constants with ionic strength follows the predictions of the Brönsted-Bjerrum theory. At zero ionic strength the variation of the rate constant with respect to temperature is reproduced by the equation k 2 0 = 1·596 × 10 21exp(−27,620 ± 187/ RT) 1.m −1sec −1.

Full Text
Paper version not known

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call

Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.