Abstract
A model for the interpretation of the 119 m Sn Mössbauer data for some tin(II) compounds in terms of the distribution of the tin valence electrons is suggested. It accounts for the positive signs of the quadrupole coupling constants ( eQV zz) observed for tin(II) compounds and for the variations in the Mössbauer parameters of triligandstannates(II) as the cation is changed. Although there is no general relationship between the chemical isomer shift and the quadrupole splitting parameters for tin(II) materials, the model does explain why approximately linear relationships are found between these parameters for particular series of triligandstannates(II).
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
