Abstract
AbstractBehind the outstanding photovoltaic performance of perovskite solar cells (PSCs), the correlation between the structural configuration of the PSCs and the mechanism of photoelectric conversion is still not fully understood. In this paper, two types of PSCs with different structural configurations, that is, mesoporous (meso) and planar, were prepared, and systematic optoelectronic transient studies were performed on these devices. Although the photovoltaic performances of the tested meso‐ and planar‐PSCs were comparable, the different structural configurations resulted in distinct charge dynamics and photoelectric conversion mechanisms. By taking the dynamic results into account, the influence of a meso‐TiO2 layer on charge accumulation, transport, and recombination was elucidated. More importantly, an excessively slow temporal response component in the optoelectronic transients was observed, which was proven to be linked to specific hysteresis phenomena in the PSCs. The experimental results collectively indicated that the hysteresis, which showed strong dependence on device structure and charge dynamics, was irrelevant to charge trapping or ferroelectricity but probably resulted from interfacial charge accumulation and/or ion migration. This work provides deep insight into the structure–function relationship in PSCs and highlights the effect of hysteresis on charge dynamics.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
