The influence of SO2 on the tolerable water content to avoid pipeline corrosion during the transportation of supercritical CO2

Abstract

A systematic study is undertaken to establish the influence of sulfur dioxide (SO2) concentration on the critical water content required to avoid substantial levels of internal corrosion during the transport of supercritical CO2 for carbon capture and storage (CCS) applications. Corrosion experiments were performed on X65 carbon steel in autoclaves containing supercritical CO2 at 80bar and 35°C in the presence of 0, 50, and 100ppm (mole) SO2. General and localized corrosion rates were determined over a period of 48h through the implementation of gravimetric analysis and surface profilometry, respectively. Analysis of corrosions products formed on the steel surface was performed using X-ray diffraction, Raman spectroscopy, and scanning electron microscopy. The results indicate that the presence of SO2 reduces the critical water content required to maintain a general corrosion rate below 0.1mm/year. Furthermore, the water content required to avoid excessive localized corrosion is far less than that to prevent significant general corrosion. Localized corrosion rates close to 1mm/year were observed in the absence of SO2 when the CO2 system was water-saturated, but below water contents of ∼1800ppm (mole) and ∼500ppm, general and localized corrosion rates (respectfully) were found to be below 0.1mm/year even in the presence of 100ppm SO2. The research presented highlights that reducing water content is a more favorable option compared to reducing SO2 content to minimize internal pipeline corrosion during transportation. Consideration is also afforded to the consumption of impurities in the closed system experiments.