Abstract

Linear relationships between the magnitudes of the /sup 29/Si isotropic chemical shifts and the number of aluminum atoms in FAU and LTA framework materials indicate second-neighbor effects and provide an alternative method of determining framework compositions from /sup 29/Si NMR spectra. Mean values for the change in chemical shift per added aluminum atom are 6.28 and 0.70 ppm for first- and second-neighbor sites, respectively. 35 references, 2 figures, 2 tables.

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