Abstract
Molecular spinning tops: Five halogen-bonded isotopologues of the CF3Cl–H2O complex have been assigned by Fourier-transform microwave spectroscopy. All complexes are symmetric-top systems with evenly spaced bonds. The free internal rotation, relative stability, and structure of these complexes were determined (see picture; Ψ, θ, and Φ: angles, a and b: axes of the monomer, and A: axis of the complex). Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
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