Abstract

The technology of the growth of cubic CuCl single crystals is described. Single crystals 7–8 mm in diameter and 40 mm in length, with a low optical density (0.107) and with satisfactory electrical resistance (7 MΩ cm), can be grown from KCl solvent. The growth conditions and the resulting optical and electrical properties of the crystals grown from molten KCl, CsCl, SrCl 2, BaCl 2 and from a molten SrCl 2- BaCl 2 mixture are investigated. KCl is the best solvent from the standpoint of single crystal growth. A mixture of 30 mole% BaCl 2+70 mole% SrCl 2 is more advantageous from the standpoint of electrical properties. The temperature profile within the solvent zone and along the crystal in axial direction during growth was determined, in addition to the temperature of the interface of the growing crystal.

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