Abstract
The B ̃ 2 Σ + - X ̃ 2 Σ + transition of CaOD near 5550 Å was studied using dye laser excitation spectroscopy. The 000-000 band was rotationally analyzed and r 0 structures were established for both states. For the B ̃ 2 Σ + state the following bond lengths were found: r CaO = 1.9697 A ̊ and r OH = 0.9179 A ̊ , while for the X ̃ 2 Σ + state r CaO = 1.9849 A ̊ and r OH = 0.9207 A ̊ .
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