The fate of cadmium in field soils of the Danubian lowland

Abstract

The susceptibility of soils to deep penetration of cadmium was assessed by measuring cadmium adsorption on soil particles <0.01 mm, easily mobile in soil macropores, and bypassing ratio. The latter is defined as a ratio of the rate of macropore flow to the rate of total (macropore and matrix) flow. Measurements were made on soils from the Danubian lowland, which is a large (1260 km 2) agriculturally managed area situated in the south-west of Slovakia, with a shallow (0.5–3.8 m deep) underlying aquifer containing about 10 km 3 of freshwater. In this study, the susceptibility of soils to deep penetration of cadmium was assessed on light, loamy-sand soil in Kalinkovo, medium heavy, loamy soil in Macov, and heavy, clay soil in Jurova. It was found that when the interaction between soil and cadmium lasted 1 min, more than 35, 32, and 48% of cadmium was adsorbed on the particles <0.01 mm in soils from Kalinkovo, Macov, and Jurova, respectively. In the case of ponding infiltration, more than 50% of water can flow via topsoil macropores in Kalinkovo, about 70% in Macov, and 96% in Jurova. This value of bypassing ratio can be met during an irrigation/rain with higher intensity then the infiltration rate into the soil matrix of studied soils. As the rains resulting in the macropore flow can occur 24 times on average in south-western Slovakia during the vegetation season, the probability of deep penetration of cadmium is very high, mainly during an initial stage of rainfall. For this reason, some mitigative agricultural practices (e.g. subsurface fertilizer banding or shallow ploughing) should be used in this region to prevent soils from the deep penetration of cadmium.