Abstract
The Gibbs energy of formation of IrO 2(s) has been measured by means of oxygen dissociation pressure measurements, and by EMF measurements using ZrO 2 (+ CaO) as the solid electrolyte. In addition, high-temperature enthalpy increments of IrO 2 have ben measured from 416 to 940 K using a drop calorimeter. A “third law” evaluation of the experimental results and data from literature has been made. For the enthalpy of formation of IrO 2(s) the value Δ H° f (298.15 K) - −(59.60 ± 0.03) kcal mole −1 has been selected. The thermodynamic functions of IrO 2(s) have been calculated in the temperature range 298–1200 K.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
