Abstract
The electron exchange reaction between U(VI) and Sn(II) was studied in various concentrations of hydrochloric acid ranging from 1·0 to 6·0 molar in water solutions. The reaction was second order overall at all HCl concentrations. The rate of the reaction and the Arrhenius parameters were found to be periodic functions of the hydrogen ion concentration. Salt effect studies showed catalysis of the reaction by iron(III) and copper (II). The catalyses indicate one electron step reductions of the U(VI).
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