The Electrochemistry of Zn3 N 2 and LiZnN : A Lithium Reaction Mechanism for Metal Nitride Electrodes

Abstract

LiZnN has been isolated by way of an electrochemical conversion reaction of with Li. We show that reversibly reacts with lithium electrochemically, exhibiting a large reduction capacity of 1325 mAh/g corresponding to the insertion of 3.7 Li per Zn. Of this initial capacity, 555 mAh/g were found to be reversible. Through the use of extensive in situ and ex situ X-ray diffraction, the reaction mechanism with lithium was identified as a conversion reaction of into LiZn and a matrix of the high pressure form of Upon oxidation, LiZn transformed into metallic Zn, while contributed to the transformation into LiZnN. This is the first identification of a reversible conversion mechanism. The formation of LiZnN as the new end member of the electrochemical reaction with lithium was identified as the cause of the irreversible loss observed during the first cycle. The and LiZn oxidation into LiZnN was found to be reversible upon subsequent cycles. Poor cycle life was mainly attributed to the electromechanical grinding of the Li-Zn alloying reaction. is also introduced as a material utilizing a similar conversion reaction but exhibiting improved cycle life. © 2002 Telcordia Technologies. All rights reserved.