Abstract

Cobalt ferrite, Copper ferrite and cobalt doped copper ferrite nanoparticles have been synthesized and characterized using different characterization methods (XRD, FTIR and FESEM). The prepared nanoparticles have been used as promising fillers of the polyvinylidene fluoride (PVDF) polymer. The PVDF/(Cu–CoFe2O4, CoFe2O4, and CuFe2O4) nanocomposites films have been prepared via a simple solution casting technique. The optical properties and the piezoelectric response of the prepared nanocomposite films have been studied. This study showed that Cu–CoFe2O4 and CoFe2O4, have enhanced the interfacial polarization density and dielectric constant. The prepared nanofillers reduced the PVDF band gap energy value. The optical conductivity value of PVDF/(Cu–CoFe2O4 and CoFe2O4) increased five times compared with the pure PVDF. Also, an increase in the piezoelectric response has been recorded by adding the nano-fillers to the pure PVDF.

Highlights

  • The energy harvesting or renewable energies, such as solar energy, wind energy, vibrational energy and ocean energy, as an alternative to the traditional energy have been exploited owing to their sustainability and environment-ecofriendly [1].One of the most important energy harvesting energies is piezoelectric technology

  • polyvinylidene fluoride (PVDF) films were prepared by a simple solution casting technique [9] selecting dimethyl formamide (NMP) as the solvent while, CoFe2O4, CuFe2O4 and Cu-CoFe2O4 nanoparticles have been used as the fillers

  • Field emission scanning electron microscopy (FESEM) JEM-ARM300F operated at 200 kV was used for topographical investigation of the prepared nanoparticles

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Summary

Conflict of Interest and Authorship Conformation Form

Manuscript title: The effect of CoFe2O4, CuFe2O4 and Cu/CoFe2O4 nanoparticles on the Optical properties and piezoelectric response of the PVDF polymer. The authors whose names are listed immediately below certify that: All authors have participated in (a) conception and design, or analysis and interpretation of the data; (b) drafting the article or revising it critically for important intellectual content; and (c) approval of the final version. This manuscript has not been submitted to, nor is under review at, another journal or other publishing venue. El-Masry (a), Rania Ramadan (b) a Basic Science Dept., Higher Engineering Institute, Thebes Academy, Cairo, Egypt b Materials Science Lab. El-Masry (a), Rania Ramadan (b) a Basic Science Dept., Higher Engineering Institute, Thebes Academy, Cairo, Egypt b Materials Science Lab. (1), Physics Department, Faculty of Science, Cairo University, Giza, Egypt

1- Introduction
Experimental techniques
Nanoparticle’s characterization
Digital storage oscilloscope
Nanoparticles characterization
Optical properties
PFM studies
Conclusion
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