Abstract

The catalytic activity of ruthenium carbonyl complexes was studied for the reduction of various Schiff bases under pressurized syngas. Ru3(CO)12 was found to be a fairly good catalyst. A solvent effect study revealed amides and pyridine to be the solvents of choice. Higher pressures of hydrogen favored the reduction. In contrast, the reaction was suppressed when higher CO pressure was applied, although a low pressure of CO (~10atm) was found to be essential.

Full Text
Paper version not known

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call

Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.