Abstract
Recently, two works were reported that the permanent electric dipole moment of the ICl A state has the same direction as that of the X state, through the analysis of electric and magnetic pendular spectra and through the direct analysis of the hyperfine structures under the Stark effect, respectively. We determined clearly and sensitively the direction of the dipole moment in the A (v=27) state of I35Cl, through the line shape analysis of the Stark modulation spectra (SMS). While the result was the same as those of previous two works, the analysis of the line shape of the SMS was so useful to determine the relative direction of the dipole moment of the upper electronic state to that in the lower state, whichever of the first-order or the second-order Stark effect the state may show.
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