Abstract
The title compound is available from the reaction of labile gold(I) chloride complexes and an excess of the ligand (tBu3P), or from the NaBH4 reduction of (tBu3P)AuCl. It forms dark red cubic crystals, [a = 14.297(1) Å at -56 °C, space group P213, Z = 4], with isolated chloride anions and [(tBu3P)2Au]+ cations of C3 symmetry, with linear two-coordinate gold centers
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