Abstract
The enthalpy of mixing of binary In–Bi melts was measured by means of a calorimetric method at T = 1023, 875, 483 K. Its concentration dependence reveals a flat minimum in the region between the intermetallic phases InBi and In2Bi. The shape of the curve of the integral enthalpy of mixing for liquid In-Bi alloys is in agreement with the assumption of a competition between InBiand In2Bi-like chemical ordering before solidification.
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