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Abstract
Magnetic susceptibility data on Cu(NH 3 ) 2 CO 3 are analyzed by the effective field approximation in addition to a cluster approach. The layer structure of Cu(NH 3 ) 2 CO 3 consists of carbonate bridged chains of copper (II) ions linked together into sheets by hydrogen bonding. The cluster model of three copper ions under the effective fields gives a nice fit with the experimental data with the intrachain exchange constant of -5.9 K and the interchain exchange constant of 5.5 K. The results are compared with those of the recent investigation by the cluster approach.
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