Abstract
AbstractThe thallium(I)‐thallium(III) electron‐exchange rate has been measured at 25° in aqueous perchloric acid‐lithium perchlorate mixtures of varying acid concentration, at three values of the ionic strength.In these mixtures no detectable medium effect exists, i.e., the specific rate constant is independent of the acid concentration at each value of the ionic strength studied.The medium effect that has been found in aqueous perchloric acid‐sodium perchlorate mixtures must therefore be explained as the result of a variation of the activity coefficients of the reacting species and not, as has been done by the majority of authors, as a result of displacement of hydrolysis equilibria.
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