Abstract

Biofuels may play a significant role in regard to carbon emission reduction in the transportation sector. Therefore, a thermochemical process for biomass conversion into synthetic chemicals and fuels is being developed at the Karlsruhe Institute of Technology (KIT) by producing process energy to achieve a desirable high carbon dioxide reduction potential. In the bioliq process, lignocellulosic biomass is first liquefied by fast pyrolysis in distributed regional plants to produce an energy-dense intermediate suitable for economic transport over long distances. Slurries of pyrolysis condensates and char, also referred to as biosyncrude, are transported to a large central gasification and synthesis plant. The bioslurry is preheated and pumped into a pressurized entrained flow gasifier, atomized with technical oxygen, and converted at > 1,200°C to an almost tar-free, low-methane syngas. Syngas - a mixture of CO and H2 - is a well-known versatile intermediate for the selectively catalyzed production of various base chemicals or synthetic fuels. At KIT, a pilot plant has been constructed together with industrial partners to demonstrate the process chain in representative scale. The process data obtained will allow for process scale-up and reliable cost estimates. In addition, practical experience is gained. The paper describes the background, principal technical concepts, and actual development status of the bioliq process. It is considered to have the potential for worldwide application in large scale since any kind of dry biomass can be used as feedstock. Thus, a significant contribution to a sustainable future energy supply could be achieved.

Highlights

  • Biofuels may play a significant role in regard to carbon emission reduction in the transportation sector

  • A well-established organic chemical industry based on various biomasses existed until about a century ago

  • CO2 removal downstream is possible with a number of absorbers; the conventional Rectisol process [41] removes all higher boiling impurities by absorption in cold methanol at ca. -50°C; this is a well-known and very efficient but expensive technology, yet one of our objectives is to look for process variants without the necessity of an expensive CO shift

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Summary

Introduction

Biofuels may play a significant role in regard to carbon emission reduction in the transportation sector. A thermochemical process for biomass conversion into synthetic chemicals and fuels is being developed at the Karlsruhe Institute of Technology (KIT) by producing process energy to achieve a desirable high carbon dioxide reduction potential. The main energy source was firewood for residential heating, cooking, and lighting, as well as serving for high-temperature processes like iron ore reduction, burning bricks and tiles, or glass melting, etc. Biochemical wine and beer production by sugar and starch fermentation. Examples are the coproducts from thermochemical charcoal production like tar and pitch, e.g., as a glue for ship construction, wood preservatives, turpentine, ‘wood spirit’ (methanol), or ‘wood vinegar’ (acetic acid), etc. It took many decades of development efforts until the major organic chemicals could be manufactured by cheaper synthetic processes from coal, crude oil, or natural gas

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