The Analytic Solution of Schrödinger Equation with Potential Function Superposed by Six Terms with Positive-power and Inverse-power Potentials

Abstract

The analytic solution of the radial Schrödinger equation is studied by using the tight coupling condition of several positive-power and inverse-power potential functions in this article. Furthermore, the precisely analytic solutions and the conditions that decide the existence of analytic solution have been searched when the potential of the radial Schrödinger equation is V(r) = α1r8 + α2r3 + α3r2 + β3r−1 + β2r−3 + β1r−4. Generally speaking, there is only an approximate solution, but not analytic solution for Schrödinger equation with several potentials' superposition. However, the conditions that decide the existence of analytic solution have been found and the analytic solution and its energy level structure are obtained for the Schrödinger equation with the potential which is motioned above in this paper. According to the single-value, finite and continuous standard of wave function in a quantum system, the authors firstly solve the asymptotic solution through the radial coordinate r → and r → 0; secondly, they make the asymptotic solutions combining with the series solutions nearby the neighborhood of irregular singularities; and then they compare the power series coefficients, deduce a series of analytic solutions of the stationary state wave function and corresponding energy level structure by tight coupling among the coefficients of potential functions for the radial Schrödinger equation; and lastly, they discuss the solutions and make conclusions.