The aluminium Kβ-band structure of andalusite, sillimanite and kyanite

The Kwoiek Area of British Columbia contains a pendant or screen of metamorphosed sedimentary and volcanic rocks almost entirely surrounded by a portion of the Coast Range Batholith, and intruded by several dozen stocks. The major metamorphic effects were produced by the quartz diorite batholithic rocks, with minor and later effects by the quartz diorite stocks. The sequence of important metamorphic reactions in the metasedimentary and metavolcanic rocks, ranging in grade from chlorite to sillimanite, is: 1. chlorite + carbonate + muscovite → epidote + biotite 2. chlorite + carbonate → actinolite + epidote 3. chlorite + muscovite → garnet + biotite 4. chlorite + epidote → garnet + hornblende 5. chlorite + muscovite → garnet + staurolite + biotite 6. chlorite + muscovite → aluminum silicate + biotite 7. muscovite + staurolite → garnet + aluminum silicate + biotite 8. staurolite → garnet + aluminum silicate Continuous reactions, occurring between reactions 5 and 7, are: A. chlorite + (high Ti) biotite + Al2O3 (from plagioclase?)→ garnet + staurolite + (low Ti) biotite + O2 B. muscovite (phengitic) → garnet + staurolite +muscovite (less phengitic) + O2 (?) Detailed electron microprobe work on garnet, staurolite, biotite, and chlorite shows that: (1) The garnet porphyroblasts are zoned according to a depletion model, called the Rayleigh depletion model, which assumes equilibrium between the edge of a growing garnet and the minerals which are unzoned, notably biotite, chlorite, and muscovite, but which assumes disequilibrium within the garnet. (2) The staurolite porphyroblasts are also zoned, and from their zoning patterns reactions A, B, and 5 are documented. Progressive reduction of iron with increasing grade of metamorphism is also inferred from the staurolite zoning patterns. (3) During a late period of falling temperature garnet continued to grow and the biotite and chlorite reequilibrated. The biotite, chlorite, and garnet edge compositions can vary from point to point in a given thin section, indicating that the volume of equilibrium at the final stage of metamorphism was only a few cubic microns. (4) The horizon within the garnet that grew at maximum temperature can be identified. The Mg/Fe ratio of this horizon, if the garnet composition is a limiting composition in the Al2O3 - K2O - FeO - MgO tetrahedron, increases systematically with increasing metamorphic grade. Biotite and chlorite compositions also show a general increase in Mg/Fe ratio with increasing metamorphic grade, but staurolite appears to show the reverse effect. (5) The Mg/Fe ratio at the maximum temperature horizon of the garnet porphyroblasts is a function of its Mn content as evidenced from the study of five garnet-bearing rocks, collected from one outcrop area, with the same assemblage but with differing proportions of minerals. An important implication of zoned minerals is that the effective composition of a system in a phase lies on the join between the homogeneous minerals (if there are two) and not within three-or- four-phase fields when a zoned mineral, such as garnet or staurolite, is present in the assemblage. Study of the three aluminum silicates found in the Kwoiek Area showed that a constant pressure change in polymorphs from andalusite to kyanite to sillimanite took place with increasing temperature. This transition series is best explained by the metastable formation of andalusite. Photographic materials on pages 15, 121, 160, 162, and 164 are essential and will not reproduce clearly on Xerox copies. Photographic copies should be ordered.

The PALMEIROPOLIS Cu-Zn (Pb) volcanogenic massive sulfide deposit, Brazil, consists of three ore bodies enclosed by hydrothermal alteration zones. The ore bodies and the alteration zones were metamorphosed under amphibolite fades conditions. The Palmeirdpolis alteration zones are characterized by a great diversity of bulk rock composition that originated a wide variety of low variance mineral assemblages. These assemblages are composed of orthoamphiboles (anthophyllite and gedrite), hornblende, biotite, garnet, staurolite, sillimanite, gahnite and, rarer, cordierite. Based on analyses of mineral chemistry aad mineral assemblages, temperatures are estimated to have been 550 - 625°C and pressures 2 - 5.5 kbar. The temperature of metamorphism that prevailed at the Palmeirdpolis deposit is comparable to other amphibolite fades massive sulfide deposits, such as Geco and Linda, Canada; Falun, Sweden; and Bleikvassli, Norway. The mineralogy of the alteration zones is similar in all these deposits even though they were metamorphosed at different pressure conditions, reflected by the crystallization of one of Al2 SiO5 phase (andalusite, sillimanite or kyanite).

Adsorption of lead(II) as a major heavy metal pollutant onto nano-adsorbents of Andalusite, Kyanite and Sillimanite was studied in a batch system. Nano­-adsorbents were prepared via crushing, using a planetary ball mill and then characterized by different analyses such as: SEM, XRD, XRF and FT-IR. Major factors affecting the adsorption process were studied including pH, adsorbents dosage, initial metal concentration and temperature. Afterward, the adsorption process was studied isothermally, kinetically, and thermodynamically. The results show that aluminum silicates polymorphs are efficient adsorbents for removal of lead(II) and the removal exceeds 90%. The Freundlich isotherm model was best fitted with the experimental data. Chemisorption may control the rate of adsorption due to following the pseudo-second-order kinetic model. Thermodynamic investigation proved low randomness, exothermic and spontaneous nature of the process.

Kyanite, sillimanite and andalusite

Metamorfismo ercinico di bassa-pressione: evoluzione tettonico-metamorfica del complesso di mandatoriccio(massiccio della Sila - Calabria)

مجموعه گرانیتوئیدی کلاه قاضی در جنوب اصفهان و در پهنه ساختاری سنندج‌- سیرجان واقع شده است. بر اساس شواهد زمین‌شناسی سن احتمالی این مجموعه ژوراسیک بالایی بوده و شامل گروه های سنگی گرانودیوریت، گرانیت و آلکالی فلدسپار گرانیت است. کانی های اصلی تشکیل‌دهنده این مجموعه شامل کوارتز، پلاژیوکلاز و فلدسپار آلکالن بوده و بیوتیت تنها کانی فرومنیزین این مجموعه نفوذی است. حضور کانی های آندالوزیت، سیلیمانیت و گارنت در این مجموعه گرانیتوئیدی نشان‌دهنده منشأ رسوبی توده های مورد بررسی است. بر اساس مطالعات صحرایی، پتروگرافی و ژئوشیمیایی، سنگ‌های مجموعه نفوذی مورد بررسی در گروه گرانیتوئیدهای نوع S قرار می گیرند و دارای ماهیت کالک‌آلکالن پتاسیم بالا و از نوع پرآلومین هستند. از لحاظ ژئوشیمیایی طیف تغییرات SiO2 در نمونه های آنالیزشده از 6/64 تا 4/74 متغیر است. الگوی تغییرات عناصر کمیاب بهنجار شده نسبت به گوشته اولیه و کندریت بیانگر غنی‌شدگی این سنگ‌ها از LILE و LREE و تهی شدگی از HFSE و HREE است. نسبت 85/0-28/0 Eu/Eu*= در نمونه های کلاه قاضی نشان‌دهنده حضور اندکی پلاژیوکلاز در باقی‌مانده ذوب در منبع است. بر اساس شواهد زمین‌شناسی، کانی شناسی و ژئوشیمیایی مجموعه نفوذی کلاه قاضی در ژوراسیک بالایی و در طی نفوذ مذاب‌های گوشته ای به داخل پوسته و ذوب‌بخشی سنگ‌های پوسته ای تشکیل شده است.

The inner zone of the Sardinia Variscan segment consists of two metamorphic complexes: I) A polymetamorphic Migmatite Complex, with migmatites showing polyphase anatectic processes, in the presence of kyanite or sillimanite. The Migmatite complex preserved decametric lenses of eclogite relicts (eclogites A) affected by high T, high- to intermediate P recrystallization under granulite facies conditions The decompressional garnet + Ca-clinopyroxene + amphibole ± orthopyroxene-bearing assemblages developed in granoblastic textures generally in no stress conditions. In most cases, only symplectite textures provide evidence for the eclogitic event. II) A medium grade, mostly metapelitic complex consisting of Grt, Ky, Stau-bearing micaschists and paragneisses includes quartzites and garnet-bearing amphibolite boudins with N-MORB chemical affinity. Relicts of eclogite assemblages were locally found in the metabasite (eclogites B). In eclogites A, the geothermobarometric parameters yield temperatures in the range 690°-760°C for minimum pressure A1.3 GPa. Pyroxene compositions accord with temperatures in excess of 700°C. In eclogites B, the thermometric calibrations provide temperatures in the range 610°-700°C for pressures 1.3-1.5 GPa, based on the jadeite content. The temperatures are consistent with the biotite+muscovite+garnet+kyanite+staurolite assemblage in the host paragneisses, and with lack of anatectic processes. The age of 457±2 Ma, obtained by U/Pb dating on one sample of Type A eclogite is interpreted as a minimum estimate for the magmatism of the eclogite protolith. A second zircon population defined an age of 403±4 Ma interpreted as dating the zircon crystallization during the high-grade event. The relationships between Types A and B eclogites, and their bearing on the regional framework (Sardinia, Ligurian Alps) are discussed.

EPR spectra of Fe3+ in andalusite and kyanite (both having formula Al2SiO5) are remeasured at bands which included 60 GHz. Results, besides the unusually large b and other spin-Hamiltonian parameters, include also the (true) g-factors. The spectra due to Fe3+Fe3+ pairs are identified in andalusite and analysed. EPR-Spektren von Fe3+ in Andalusit and Kyanit (beide mit der Formel Al2SiO5) werden erneut bei Frequenzen gemessen, die 60 GHz einschliesen. Als Ergebnis werden, neben dem ungewohnlich grosen b-Wert und anderen Spin-Hamiltonparametern, die (wahren) g-Faktoren erhalten. Durch Fe3+Fe3+-Paare hervorgerufene Spektren werden in Andalusit identifiziert und analysiert.

Andalusite in California and kyanite in North Carolina

There is a typical assemblage of garnet + kyanite + microperthite + quartz + rutile in high-pressure (HP) felsic granulite of Qinling complex in Songshugou area. East Qinling. The HP granulite was formed at 800 -900℃ and 1.3 -1.6GPa and has experienced two stages of retrograde metamorphism at 600- 650 ℃, 0.8-1.0GPa and 500-600℃, 0.3-0.6GPa, forming two retrograde metamorphic assemblages of margarite + plagiodase (PlI)+quartz and sillimanite + biotite + plagioclase(PlII) + microdine+quartz, respectively. They construct a two-stage clockwise P-T path which shows down-pressure cooling in both early and late stage.

VIII. The structure of cyanite