Abstract

Chemical composition and rheological properties of agar isolated from Gelidium purpurascens, the agar after alkaline treatment, and a commercial agar are presented. The agar and alkali-treated agar gave weaker gels, as measured with an Instron 1122, than those of commercial agar. Xylose, glucose and glucuronic acid in the agar were removed together with 86% of the nitrogen content on alkaline treatment, indicating occurrence of these residues as carbohydrate-protein complexes. Sequential extraction of the alga accounted for low yields of agar as losses incurred on ethanol precipitation. Acid treatment of the residue from exhaustive aqueous extraction of the alga liberated a further 10% agar with increased gel strengths despite increased glucose inclusion, suggesting a lack of involvement of these ‘contaminant’ carbohydrate-protein residues in helix coil formation during gelling.

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