Abstract
Homochiral exo- and endo-[4-2H]-4-protoadamantyl substrates have been found to rearrange with the formation of enantiomerically pure [1-2H]-2-adamantanol; the data indicate that bridged and open 2-adamantyl cations interconvert slowly, in contrast to analogous 4-protoadamantyl cations.
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More From: Journal of the Chemical Society, Chemical Communications
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