Abstract
The controversial interpretation on the XUV spectra of PH 3 and SiH 4 have been examined experimentally and theoretically. An assigned consistent with measured 2p-absroption spectra of gaseous and solid SiH 4 and PH 3, and with CI calculation on core-excited states of SiH 4 is presented. The predictions of the equivalent ionic core virtual orbital model are confirmed. Term-values for core-excited states differ systematically from those for valence-excited states.
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