Abstract
The thermal decomposition course of the MnII oxysalts Mn(NO3)2·4H2O, MnC2O4·2H2O and MnCO3 has been examined in different gaseous atmospheres by thermogravimetry and differential thermal analysis. The solid-phase decomposition products at some selected temperatures were characterized by various bulk and surface analytical techniques. The results were used to assign the thermochemical events encountered in the decomposition course. A complex reaction interface chemistry is implied. It is concluded that the thermochemical behaviour of MnII is largely dependent on the nature of the anionic atmosphere and the volatile component being released.
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