Temperature dependence (300 to 12k) of the structural and electronic properties of the molecular charge - transfer salt ET/sub 3/Cl/sub 2/,2H/sub 2/O

D Chasseau,V Hays,P Day,J Gaultier,M Kurmoo,S Hebrard,G Bravic,L Ducassse

doi:10.1109/stsm.1994.834922

Temperature dependence (300 to 12k) of the structural and electronic properties of the molecular charge - transfer salt ET/sub 3/Cl/sub 2/,2H/sub 2/O

D Chasseau, V Hays + Show 6 more

https://doi.org/10.1109/stsm.1994.834922

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Publication Date: Jan 1, 1994

Affiliation: Laboratoire de Cristallographie et Sciences des Matériaux, Royal Institution of Great Britain, Faculty of 1000 (United Kingdom)

#Transfer Salt #Molecular Charge-transfer Salt + Show 8 more

Abstract
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Abstract

Summary form only given. The molecular charge-transfer salt (BEDT-TFF) /sub 3/Cl/sub 2/,2H/sub 2/O undergoes a metal-insulator transition at about 100K and becomes superconducting under pressure (10kbar) at 5K. The isobaric thermal expansions are calculated from the values of the lattice parameters (300 to 12K at ambient pressure). The electronic properties are deduced from the ambient pressure (295, 130 and 12K) crystal structures.

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