Abstract
1. A study has been made of the polarographic behavior of semiand thiosemicarbazones of acetone, methyl ethyl ketone, methyl n-propyl'ketone, methyl isopropyl ketone, methyl n-butyl ketone, methyl n-amyl ke'tone, methyl n-hexyl ketone, diethyl ketone, cyclopentanone, cyclohexanone, and pinacoline semicarbazone. 2. It is proposed that the compounds investigated show a structure of ensemiand enthiosemicarbazine type in water-alcohol solutions. 3. The effect of alkyl groups on the ease of reduction of methyl alkyl ketone derivatives is explained from the point of view of present-day concepts in organic chemistry.
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